KINETIC RESOLUTION OF KETONE CYANOHYDRIN ACETATES WITH A MICROBIAL ENZYME

DOI: 10.1016/S0040-4039(00)88486-5

Source and publish data:

Tetrahedron Letters p. 6957 - 6960 (1988)

Update date:2022-07-29

Topics:

Authors:

Ohta, Hiromichi

Kimura,Yoichi

Sugano, Yasushi

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Article abstract of DOI:10.1016/S0040-4039(00)88486-5

Incubation of dl-1-cyano-1-metylalkyl (or alkenyl) acatates (methyl ketone cyanohydrin acetates) with cells of Pichia miso IAM 4682 afforded optically active acetates and the corresponding ketones via asymmetric hydrolysis.Resulting (S)-2-cyano-2-undecyl acetate was converted to the aminofuranone derivative without losing its optical purity.

Full text of DOI:10.1016/S0040-4039(00)88486-5

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