Tetrahedron Letters p. 4847 - 4850 (1988)
Update date:2022-07-31
Topics:
Sasaki, Mitsuru
Collin, Jacqueline
Kagan, Henri B.
A new synthesis of 1,2-glycol monoethers has been achived by utilizing decarbonylation of α-alkoxyacid chlorides mediated by samarium diiodide in the presence of ketones.This one-pot reaction works within a few minutes at room temperature.The structure of α-alkoxyacid chlorides (R2,R3)C(OR1)COCl2 tolerates various substitution patterns (R2=R3=H; R2=H; R3=Me or R2=R3=Me).
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Doi:10.1039/b912724k
(2009)Doi:10.1007/BF00763671
(1988)Doi:10.1021/jo100928g
(2010)Doi:10.1021/jo901535c
(2009)Doi:10.1016/j.tetlet.2009.09.105
(2009)Doi:10.1055/s-0036-1589134
(2018)
