SYNTHESIS OF 1,2-GLYCOL MONOETHERS UTILIZING DECARBONYLATION OF α-ALKOXYACID CHLORIDES MEDIATED BY SAMARIUM DIIODIDE

DOI: 10.1016/S0040-4039(00)80624-3

Source and publish data:

Tetrahedron Letters p. 4847 - 4850 (1988)

Update date:2022-07-31

Topics:

Authors:

Sasaki, Mitsuru

Collin, Jacqueline

Kagan, Henri B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80624-3

A new synthesis of 1,2-glycol monoethers has been achived by utilizing decarbonylation of α-alkoxyacid chlorides mediated by samarium diiodide in the presence of ketones.This one-pot reaction works within a few minutes at room temperature.The structure of α-alkoxyacid chlorides (R²,R³)C(OR¹)COCl2 tolerates various substitution patterns (R²=R³=H; R²=H; R³=Me or R²=R³=Me).

Full text of DOI:10.1016/S0040-4039(00)80624-3

Products guided by the article

Product name:C₃₃H₅₂O₃Si

Cas No:119720-67-1

R&D Labs maybe for 119720-67-1

Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China
A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
Xiamen Huasing Chemicals Co.Ltd.

Contact:0086-592-6228397

Address:NO.24, Xinglin North 2nd Road,Jimei district
Zipont chem(wuhan）Tech co.，Ltd

Contact:+86-27-87587198

Address:wuhan

Relevant to this article

Synthesis of fluorophosphonylated acyclic nucleotide analogues via copper(I)-catalyzed Huisgen 1-3 dipolar cycloaddition

Doi:10.1039/b912724k
(2009)
SYNTHESIS AND TRANSFORMATIONS OF 3α-HYDROXY-5α-ANDROST-11-EN-17-ONE

Doi:10.1007/BF00763671
(1988)
Modular approach to triazole-linked 1,6-α-d-oligomannosides to the discovery of inhibitors of mycobacterium tuberculosis cell wall synthetase

Doi:10.1021/jo100928g
(2010)
Synthesis of stannyl porphyrins and porphyrin dimers via stille coupling and their ¹¹⁹Sn NMR and fluorescence properties

Doi:10.1021/jo901535c
(2009)
An improved synthesis of 1-methyl-1H-pyrazole-4-boronic acid pinacol ester and its corresponding lithium hydroxy ate complex: application in Suzuki couplings

Doi:10.1016/j.tetlet.2009.09.105
(2009)
Scope and Optimization of the Double Knorr Cyclization: Synthesis of Novel Symmetrical and Unsymmetrical Tricyclic 1,8-Diazaanthraquinones

Doi:10.1055/s-0036-1589134
(2018)

Article Doi