SYNTHESIS OF 1,2-GLYCOL MONOETHERS UTILIZING DECARBONYLATION OF α-ALKOXYACID CHLORIDES MEDIATED BY SAMARIUM DIIODIDE

DOI: 10.1016/S0040-4039(00)80624-3

Source and publish data:

Tetrahedron Letters p. 4847 - 4850 (1988)

Update date:2022-07-31

Topics:

Authors:

Sasaki, Mitsuru

Collin, Jacqueline

Kagan, Henri B.

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Article abstract of DOI:10.1016/S0040-4039(00)80624-3

A new synthesis of 1,2-glycol monoethers has been achived by utilizing decarbonylation of α-alkoxyacid chlorides mediated by samarium diiodide in the presence of ketones.This one-pot reaction works within a few minutes at room temperature.The structure of α-alkoxyacid chlorides (R²,R³)C(OR¹)COCl2 tolerates various substitution patterns (R²=R³=H; R²=H; R³=Me or R²=R³=Me).

Full text of DOI:10.1016/S0040-4039(00)80624-3

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