SYNTHESIS OF 1,2-GLYCOL MONOETHERS UTILIZING DECARBONYLATION OF α-ALKOXYACID CHLORIDES MEDIATED BY SAMARIUM DIIODIDE

DOI: 10.1016/S0040-4039(00)80624-3

Source and publish data:

Tetrahedron Letters p. 4847 - 4850 (1988)

Update date:2022-07-31

Topics:

Authors:

Sasaki, Mitsuru

Collin, Jacqueline

Kagan, Henri B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80624-3

A new synthesis of 1,2-glycol monoethers has been achived by utilizing decarbonylation of α-alkoxyacid chlorides mediated by samarium diiodide in the presence of ketones.This one-pot reaction works within a few minutes at room temperature.The structure of α-alkoxyacid chlorides (R²,R³)C(OR¹)COCl2 tolerates various substitution patterns (R²=R³=H; R²=H; R³=Me or R²=R³=Me).

Full text of DOI:10.1016/S0040-4039(00)80624-3

Products guided by the article

Product name:C₃₃H₅₂O₃Si

Cas No:119720-67-1

R&D Labs maybe for 119720-67-1

Nanjing Ruizhi Industry & Technologh Co.，Ltd.

Contact:+86-25-86808110

Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
xujianqiang

Contact:86-21-57725962

Address:shanghai
JADECHEM NINGBO CO.,LTD.

Contact:+86-574-89075960

Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
Shanghai Hohance Chemical Co., ltd

Contact:13914753421

Address:Fl.5；Bld. 70, Lane 1500; Xinfei Road

Relevant to this article

Synthesis of fluorophosphonylated acyclic nucleotide analogues via copper(I)-catalyzed Huisgen 1-3 dipolar cycloaddition

Doi:10.1039/b912724k
(2009)
SYNTHESIS AND TRANSFORMATIONS OF 3α-HYDROXY-5α-ANDROST-11-EN-17-ONE

Doi:10.1007/BF00763671
(1988)
Modular approach to triazole-linked 1,6-α-d-oligomannosides to the discovery of inhibitors of mycobacterium tuberculosis cell wall synthetase

Doi:10.1021/jo100928g
(2010)
Synthesis of stannyl porphyrins and porphyrin dimers via stille coupling and their ¹¹⁹Sn NMR and fluorescence properties

Doi:10.1021/jo901535c
(2009)
An improved synthesis of 1-methyl-1H-pyrazole-4-boronic acid pinacol ester and its corresponding lithium hydroxy ate complex: application in Suzuki couplings

Doi:10.1016/j.tetlet.2009.09.105
(2009)
Scope and Optimization of the Double Knorr Cyclization: Synthesis of Novel Symmetrical and Unsymmetrical Tricyclic 1,8-Diazaanthraquinones

Doi:10.1055/s-0036-1589134
(2018)

Article Doi