SYNTHESIS OF 2-(PHENYLTRIFLUOROACETYLAMINO)-3-(TRIMETHYLSILOXY) ALKANOIC ACID AND N-PHENYL-N-TRIFLUOROACETYLDEHYDROAMINO ACID ESTERS

DOI: 10.1016/S0040-4020(01)86042-7

Source and publish data:

Tetrahedron p. 5355 - 5360 (1988)

Update date:2022-09-26

Topics:

Authors:

Jacobsen-Bauer, Andrea

Simchen, Gerhard

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Article abstract of DOI:10.1016/S0040-4020(01)86042-7

Reaction of aromatic aldehydes 4 with the ketene acetal 3 in presence of zinc bromide affords methyl 2-(phenyltrifluoroacetylamino)-3-trimethylsiloxy alkanoates 5.Elimination of trimethylsilanole from 5 by means of trifluoroacetic acid anhydride yields (E

Full text of DOI:10.1016/S0040-4020(01)86042-7

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Product name:2-[Phenyl-(2,2,2-trifluoro-acetyl)-amino]-3-p-tolyl-3-trimethylsilanyloxy-propionic acid methyl ester

Cas No:119799-72-3

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