SYNTHESIS OF SILYLATED 1,3-DIENES VIA THE CARBOPALLADATION OF ALLENES.

DOI: 10.1016/S0040-4039(00)80167-7

Source and publish data:

Tetrahedron Letters p. 627 - 630 (1988)

Update date:2022-09-26

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Authors:

Cazes, Bernard

Colovray, Veronique

Gore, Jacques

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Article abstract of DOI:10.1016/S0040-4039(00)80167-7

Catalytic carbopalladation of allenes 1 or 2 with silylated vinyl bromides 3 gives ?-allyl palladium complexes 5 which are trapped by stabilized enolates and lead to β-difunctionalized silylated dienes 7-9.

Full text of DOI:10.1016/S0040-4039(00)80167-7

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