SYNTHESIS OF SILYLATED 1,3-DIENES VIA THE CARBOPALLADATION OF ALLENES.

DOI: 10.1016/S0040-4039(00)80167-7

Source and publish data:

Tetrahedron Letters p. 627 - 630 (1988)

Update date:2022-09-26

Topics:

Authors:

Cazes, Bernard

Colovray, Veronique

Gore, Jacques

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80167-7

Catalytic carbopalladation of allenes 1 or 2 with silylated vinyl bromides 3 gives ?-allyl palladium complexes 5 which are trapped by stabilized enolates and lead to β-difunctionalized silylated dienes 7-9.

Full text of DOI:10.1016/S0040-4039(00)80167-7

Products guided by the article

Product name:2-[1-((E)-1-Methylene-3-trimethylsilanyl-allyl)-octyl]-malonic acid dimethyl ester

Cas No:119841-11-1

R&D Labs maybe for 119841-11-1

Hangzhou Sartort Biopharma Co., Ltd

website:http://www.sartort.com

Contact:86-571-87039693

Address:No. 57, Tech Park Road, Hangzhou, Zhejiang, China
Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan
Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road

Relevant to this article

Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane

Doi:10.1016/j.tet.2004.06.035
(2004)
Doi:10.1021/jo00864a039
(1976)
Four novel coordination polymers of transition metals built using a semi rigid oxygen donor ligand: Crystal structures, novel topology and emission studies

Doi:10.1016/j.poly.2012.10.045
(2013)
Sulfonation and sulfation in the reactions of the chloro- and dichlorophenols, 3-fluorophenol and (2,3-, 2,4- and 3,4-dichlorophenoxy)acetic acid with concentrated aqueous sulfuric acid and sulfur trioxide

Doi:10.1002/recl.19881070303
(1988)
6-Deoxy-6-(dimethylphenylsilyl)-1,2:3,4-di-O-isopropylidene-β-L-altropyranose: Synthesis via hydrosilation, and reactivity

Doi:10.1016/0008-6215(88)80030-2
(1988)
DBU-Catalyzed, facile and efficient method for synthesis of spirocyclic 2-oxindole derivatives with incorporated 6-amino-4H-pyridazines and fused derivatives via [3+3] atom combination

Doi:10.1016/j.tet.2009.09.081
(2009)

Article Doi