
Tetrahedron p. 8685 - 8698 (1994)
Update date:2022-07-30
Topics:
Shing, Tony K. M.
Gillhouley, John G.
(+)-Altholactone 1 and (+)-7-epi-altholactone 3 were constructed from D-gulonolactone whereas their respective enantiomers (-)-altholactone 2 and (-)-7-epi-altholactone 4 were synthesized from D-mannose, involving stereocontrolled reduction of the lactols 21 as a key step.
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