The First Transition Metal Complex Containing a Co-ordinated Vinylcyclopropene and its Photochemical Ring Expansion to give an η4-Cyclobutadiene Ligand

DOI: 10.1039/c39880000319

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 319 - 320 (1988)

Update date:2022-08-04

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Authors:

Hemond, Richard C.

Hughes, Russell P.

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Article abstract of DOI:10.1039/c39880000319

1,2,3-Triphenyl-3-trifluorovinylcycloprop-1-ene (1a) reacts with to give the first example of a complex (3) containing a co-ordinated η²-vinylcyclopropene; on subsequent irradiation an unprecedented ring expansion reaction occurs give the η⁴-cyclobutadiene complex (4).

Full text of DOI:10.1039/c39880000319

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