Novel Hydrolysis Pathways of Dimesityldifluorosilane via an Anionic Five-Coordinated Silicate and a Hydrogen-Bonded Bisilonate. Model Intermediates in the Sol-Gel Process

DOI: 10.1021/ja00191a023

Source and publish data:

Journal of the American Chemical Society p. 3250 - 3258 (1989)

Update date:2022-09-26

Topics: Hydrolysis Anionic

Authors:

Johnson, Stephen E.

Deiters, Joan A.

Day, Roberta O.

Holmes, Robert R.

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Article abstract of DOI:10.1021/ja00191a023

Reaction of dimesityldifluorosilane, Mes2SiF2, with Et4NF*2H2O in acetonitrile resulted in the formation of the five-coordinated complexes, , , the hydrogen bisilonate, 2 (2), and the disiloxane, (Mes2Si

Full text of DOI:10.1021/ja00191a023

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