Journal of the American Chemical Society p. 2995 - 3000 (1989)
Update date:2022-08-02
Topics:
Leblanc, Yves
Fitzsimmons, Brian J.
Springer, James P.
Rokach, Joshua
The <4+2> cycloaddition reaction of dibenzyl azodicarboxylate and glycals allows the stereoselective introduction of an amino function at C-2 of a carbohydrate.Very good results were obtained with both furanoid and pyranoid glycals, except when triacetylglucal (TAG) was used as the substrate.In some instances the course of the reaction was found to be concentration dependent.
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