Asymmetric Induction in Intramolecular Ene Reactions of Chiral 1,7-Dienes: A Diastereo- and Enantioselective Synthesis of Substituted Cyclohexanes

DOI: 10.1021/jo00274a031

Source and publish data:

Journal of Organic Chemistry p. 3120 - 3129 (1989)

Update date:2022-08-03

Topics:

Authors:

Tietze, Lutz F.

Beifuss, Uwe

Ruther, Michael

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00274a031

The asymmetric induction in intramolecular thermal and Lewis acid catalyzed ene reactions of chiral 1,7-dienes 9 activated by two electron-withdrawing groups on the enophile is studied.The cycloadducts resulting from intramolecular ene, sequential ene, an

Full text of DOI:10.1021/jo00274a031

Products guided by the article

Product name:(4aR,6R,8aR)-4-cyano-1,1,6-trimethyl-3,4,4a,5,6,7,8,8a-octahydro-1H-2-benzopyran-3-one

Cas No:120230-04-8

R&D Labs maybe for 120230-04-8

SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:86-574-13989382828

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Sino-Japan Chemical Co., Ltd.

website:http://www.sjc.com.tw

Contact:(886) 2-2396-6223

Address:14Fl., No. 99. Sec. 2, Jen Ai Road
Jinan Finer Chemical Co., Ltd

website:https://www.finerchem.com

Contact:+86-531-88989536

Address:New Material Industrial Park, Jinan City, China
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
Shanghai chemrole co.,ltd

Contact:021-50278900

Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china

Relevant to this article

Enantiopure derivatives of aza-baylis-hillman adducts by subsequent sn'-sn' reactions of acylcarbamates bearing a chiral auxiliary

Doi:10.3390/molecules14082824
(2009)
Doi:10.1016/S0040-4039(00)77967-6
(1976)
Nickel-Catalyzed Double Dehydrogenative Coupling of Secondary Alcohols and β-Amino Alcohols to Access Substituted Pyrroles

Doi:10.1021/acs.joc.9b01819
(2019)
Unbridged 1- and 2-substituted bis(silylindenyl) zirconium(IV) and hafnium(IV) dichloride complexes as catalyst precursors for ethylene polymerization

Doi:10.1016/j.poly.2017.07.028
(2017)
A Nanocrystal Catalyst Incorporating a Surface Bound Transition Metal to Induce Photocatalytic Sequential Electron Transfer Events

Doi:10.1021/jacs.1c00503
(2021)
Carbocation-forming reactions in dimethyl sulfoxide

Doi:10.1021/jo026468x
(2003)

Article Doi