A New Class of Dihydrogen Complexes containing Oxygen Donor Ligands. Preparation of RuH(η2-H2)(OCOCF3)2 and of the Equilibrated Mixture RuH2(OCOCF3)22/Ru(η2-H2)(OCOCF3)22

DOI: 10.1039/c39890000155

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 155 - 157 (1989)

Update date:2022-09-26

Topics:

Authors:

Arliguie, Therese

Chaudret, Bruno

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890000155

The protonation of RuH2(H2)2(PCy3)2 (1) (Cy = cyclohexyl) with CF3CO2H in acetone leads to the hydrido dihydrogen derivative RuH(H2)(OCOCF3)(PCy3)2 (2), which reacts further in hexane to yield a very reactive Ru^IV dihydride, RuH2(OCOCF3)2(PCy3)

Full text of DOI:10.1039/c39890000155

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ru(η2-H2)(OCOCF3)2{P(C6H11)3}2

Cas No:120389-49-3

R&D Labs maybe for 120389-49-3

JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Deer Chemicals Co., Ltd.

Contact:+86-13666670345

Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang
Hebei Kangtai Pharmaceutical Co.,Ltd

Contact:+86-0317-3512963

Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
BioBioPha Co., Ltd

Contact:+86-871-65217109

Address:132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences

Relevant to this article

Magnetic g-C₃N₄ nanocomposite-catalyzed environmentally benign aminolysis of epoxide

Doi:10.1007/s11164-017-3176-0
(2018)
Highly efficient and mild method for regioselective de-O-benzylation of saccharides by Co₂(CO)₈-Et₃SiH-CO reagent system

Doi:10.1021/ol902717y
(2010)
Catalytic asymmetric conjugate addition of dialkylzinc reagents to α,β-unsaturated sulfones

Doi:10.1039/b917269f
(2010)
Novel approach to synthesis of substituted 3-aminoquinolines from nitroarenes and protected ethyl aminocrotonate

Doi:10.1016/j.tet.2009.11.060
(2010)
Synthesis, structures, and optical properties of heteroarene-fused dispiro compounds

Doi:10.1021/jo902482n
(2010)
Classical benzotriazole-mediated α-aminoalkylations of alkynes: Synthesis and characterization of alk-2-yn-1-amines as amphiphilic materials

Doi:10.1002/hlca.200790173
(2007)

Article Doi