A New Class of Dihydrogen Complexes containing Oxygen Donor Ligands. Preparation of RuH(η2-H2)(OCOCF3)2 and of the Equilibrated Mixture RuH2(OCOCF3)22/Ru(η2-H2)(OCOCF3)22

DOI: 10.1039/c39890000155

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 155 - 157 (1989)

Update date:2022-09-26

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Authors:

Arliguie, Therese

Chaudret, Bruno

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Article abstract of DOI:10.1039/c39890000155

The protonation of RuH2(H2)2(PCy3)2 (1) (Cy = cyclohexyl) with CF3CO2H in acetone leads to the hydrido dihydrogen derivative RuH(H2)(OCOCF3)(PCy3)2 (2), which reacts further in hexane to yield a very reactive Ru^IV dihydride, RuH2(OCOCF3)2(PCy3)

Full text of DOI:10.1039/c39890000155

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