Journal of the Chemical Society. Chemical communications p. 155 - 157 (1989)
Update date:2022-09-26
Topics:
Arliguie, Therese
Chaudret, Bruno
The protonation of RuH2(H2)2(PCy3)2 (1) (Cy = cyclohexyl) with CF3CO2H in acetone leads to the hydrido dihydrogen derivative RuH(H2)(OCOCF3)(PCy3)2 (2), which reacts further in hexane to yield a very reactive RuIV dihydride, RuH2(OCOCF3)2(PCy3)
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