Generation of a μ3-Vinylidene Ligand via Step-wise Cleavage of 1,1-Bis(diphenylphosphino)ethylene at Di- and Tri-iron Centres

DOI: 10.1039/c39880000673

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 673 - 675 (1988)

Update date:2022-08-05

Topics:

Authors:

Grist, Nigel J.

Hogarth, Graeme

Knox, Selby A. R.

Lloyd, Brian R.

Morton, David A. V.

Orpen, A. Guy

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Article abstract of DOI:10.1039/c39880000673

Through a sequence of thermally- and photochemically-induced steps the 1,1-bis(diphenylphosphino)ethylene ligand in > or > is fragmented to generate the μ₃-vinylidene complex 3-CCH2)>; the structures of the latter and of two 'phospha-allene' precursors and 3-Ph2PCCH2)> have been established by X-ray diffraction.

Full text of DOI:10.1039/c39880000673

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