Regiochemical Control in the Intramolecular Addition of Allylstannanes and Allylsilanes to 2,3-Epoxy Ethers: Preparation of Functionalized Oxepanes

DOI: 10.1021/jo00274a030

Source and publish data:

Journal of Organic Chemistry p. 3114 - 3120 (1989)

Update date:2022-09-26

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Authors:

Molander, Gary A.

Andrews, Steven W.

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Article abstract of DOI:10.1021/jo00274a030

Lewis acid directed intramolecular additions of allylstannanes and allylsilanes to 2,3-epoxy ether substrates are described.Excellent regiocontrol and diastereoselectivity is achieved by titanium(IV) chloride promoted cyclization of substituted epoxy ethe

Full text of DOI:10.1021/jo00274a030

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