Photoreaction of the Adduct between (η-Cyclopentadienyl)(1,2-dicyano-1,2-ethylenedithiolato)cobalt(III) and Tributylphosphine

DOI: 10.1246/cl.1990.1089

Source and publish data:

Chemistry Letters p. 1089 - 1092 (1990)

Update date:2022-07-29

Topics:

Authors:

Hatano, Hiroshi

Kajitani, Masatsugu

Akiyama, Takeo

Sakaguchi, Yoshio

Nakamura, Junko

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.1089

The title complex gives and phosphine oxide (O = PBu3) under irradiation with methylene blue or rose bengal as sensitizer in the presence of oxygen.This reaction proceeds via oxidative elimination of the coordinated phosphine by singlet oxygen.Under irradiation with 254 nm light, the adduct plays the role of a triplet sensitizer.

Full text of DOI:10.1246/cl.1990.1089

Products guided by the article

Product name:{(η-cyclopentadienyl)(1,2-dicyano-1,2-ethylenedithiolato)cobalt(III)}

Cas No:12082-04-1

R&D Labs maybe for 12082-04-1

SAGECHEM LIMITED

website:http://www.sagechem.com

Contact:+86-571-86818502

Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Aecochem Corp.

website:http://www.aecochemical.com

Contact:+86-592 599 8717

Address:No 611 Sishui Road,Huli
Taizhou Crene Biotechnology co.ltd

Contact:86-576-88813233 88205808

Address:Economic Developed Zone of Taizhou Zhejiang China
Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District

Relevant to this article

Self-catalytic, solvent-free or in/on water protocol: aza-Friedel-Crafts reactions between 3,4-dihydroisoquinoline and 1- or 2-naphthols

Doi:10.1016/j.tet.2009.11.008
(2010)
Influence of the size of aromatic chelate ligands on the one-dimensional structures of copper(II) 4,4?-oxy-bis(benzoate) coordination polymers

Doi:10.1134/S1070328409060141
(2009)
NUCLEOPHILIC DISPLACEMENT OF THE TRIFLATE GROUP IN BENZYL 3-O-BENZYL-4,6-O-BENZYLIDENE-2-O-TRIFLUOROMETHANESULFONYL-α-D-MANNOPYRANOSIDE

Doi:10.1016/0008-6215(89)84013-3
(1989)
SYNTHESIS OF VINYLIC LACTONES VIA PALLADIUM-CATALYZED COUPLING OF VINYLIC HALIDES OR TRIFLATES AND UNSATURATED CARBOXYLIC ACIDS

Doi:10.1016/S0040-4039(00)82356-4
(1988)
Catalytic asymmetric oxidative carbonylation-induced kinetic resolution of sterically hindered benzylamines to chiral isoindolinones

Doi:10.1039/d0cc07218d
(2021)
Doi:10.1021/ja01203a051
(1947)

Article Doi