Photoreaction of the Adduct between (η-Cyclopentadienyl)(1,2-dicyano-1,2-ethylenedithiolato)cobalt(III) and Tributylphosphine

DOI: 10.1246/cl.1990.1089

Source and publish data:

Chemistry Letters p. 1089 - 1092 (1990)

Update date:2022-07-29

Topics:

Authors:

Hatano, Hiroshi

Kajitani, Masatsugu

Akiyama, Takeo

Sakaguchi, Yoshio

Nakamura, Junko

et al. et al.

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Article abstract of DOI:10.1246/cl.1990.1089

The title complex gives and phosphine oxide (O = PBu3) under irradiation with methylene blue or rose bengal as sensitizer in the presence of oxygen.This reaction proceeds via oxidative elimination of the coordinated phosphine by singlet oxygen.Under irradiation with 254 nm light, the adduct plays the role of a triplet sensitizer.

Full text of DOI:10.1246/cl.1990.1089

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