DIASTEREOSELECTIVE SYNTHESE VON α,γ-AMINOALKOHOLEN DURCH INTRAMOLEKULARE 1,3-DIPOLARE CYCLOADDITION VON NITRONEN MIT ALLYLTHIOETHER-GRUPPIERUNG UND ANSCHLIESSENDE REDUZIERENDE RINGOEFFNUNG

DOI: 10.1016/S0040-4039(00)82182-6

Source and publish data:

Tetrahedron Letters p. 5755 - 5758 (1988)

Update date:2022-08-05

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Authors:

Aurich, Hans Guenter

Moebus, Klaus-Dieter

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Article abstract of DOI:10.1016/S0040-4039(00)82182-6

The bicyclic compounds 2 and 4 are formed by intramolecular 1,3-dipolar cycloaddition of the nitrones 1 and 3, respectively.Reductive cleavage of 2a and 4a with desulfurization yields α,γ-aminoalcohols 7 and 9, respectively, as diastereomerically pure com

Full text of DOI:10.1016/S0040-4039(00)82182-6

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