Journal of Fluorine Chemistry p. 361 - 376 (1989)
Update date:2022-08-02
Topics:
Aubert, Corinne
Begue, Jean-Pierre
Charpentier-Morize, Micheline
Nee, Gerard
Langlois, Bernard
Alkylation of Ethyl 4,4,4 trifluoroacetylacetate (ETFAA) 1 by alkyl halides presented some typical features.The reaction was very slow and led preferentially to O-alkylated products.However, with activated halides and under some peculiar conditions, it was possible to obtain selectively C-alkylated products 3 and 4 in good yields.
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