Tetrahedron Letters p. 6921 - 6924 (1988)
Update date:2022-08-03
Topics:
Adams, Florian
Gompper, Rudolf
Hohenester, Achim
Wagner, Hans-Ulrich
Calculated heats of formation of thio and amino substituted planar triplet trimethylenemethanes are comparable to those of the corresponding methylenecyclopropanes.Y-Aromatic <1>-tris(1,3-dithiol-2-yl)<0.0.0>monomethinium bistetrafluoroborates, prepared via novel 6,6-diformyl-1,3-dithiafulvenes and the corresponding bisdithioacetals, can be reversibly reduced to stable radical cations and neutral compounds tentatively assigned as stable trimethylenemethanes.
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Doi:10.1039/c39890000375
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(1988)
