Journal of the Chemical Society. Perkin Transactions 1 (2001) p. 1581 - 1587 (2002)
Update date:2022-08-04
Topics: Polyenes Total synthesis Optically active Carotenoids Mytiloxanthin
Tode, Chisato
Yamano, Yumiko
Ito, Masayoshi
Biomimetic synthesis of mytiloxanthin 1 was accomplished with stereoselective rearrangement of the tetrasubstituted epoxide 5 as a key reaction. This is the first total synthesis of optically active all-E mytiloxanthin 1.
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