Functionalization of Olefins by Alkoximidoylnitrenes

DOI: 10.1021/jo00277a037

Source and publish data:

Journal of Organic Chemistry p. 3945 - 3952 (1989)

Update date:2022-08-04

Topics: Functionalization Olefins

Authors:

Subbaraj, A.

Rao, O. Subba

Lwowski, Walter

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Article abstract of DOI:10.1021/jo00277a037

(N-Cyano- and N-(methylsulfonyl)alkoxycarbimidoyl)nitrenes, generated in situ from the corresponding azides by 300-nm UV-light, convert a variety of olefins cleanly and stereospecifically to the corresponding aziridines.These can readily be hydrolyzed to

Full text of DOI:10.1021/jo00277a037

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