Sigmatropic Rearrangements of N-Benzyl-N-methyl-N-(2-alkenyl)ammonium N-Methylides

DOI: 10.1055/s-1988-27778

Source and publish data:

Synthesis p. 988 - 990 (1988)

Update date:2022-08-02

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Authors:

Sugiyama, Hidehiko

Sato, Yoshiro

Shirai, Naohiro

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Article abstract of DOI:10.1055/s-1988-27778

Fluoride-ion induced desilylation of N-benzyl-N-methyl-N-(2-alkenyl)-N-<(trimethylsilyl)methyl>ammonium halides gave N-methylide intermediates which were isomerized to N-methyl-N-(2-alkenyl)-2-methylbenzylamines (Sommelet-Hauser rearrangement products) an

Full text of DOI:10.1055/s-1988-27778

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