α-Aminophosphonate derivatives as nucleophiles in diastereoselective and enantioselective palladium catalysed allylic substitution reactions

DOI: 10.1016/0957-4166(95)00059-X

Source and publish data:

Tetrahedron Asymmetry p. 679 - 682 (1995)

Update date:2022-07-29

Topics:

Authors:

Baldwin Baldwin

Williams

Beckett Beckett

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Article abstract of DOI:10.1016/0957-4166(95)00059-X

The palladium catalysed reaction between allyl acetates and Schiff base derivatives of α-aminophosphonates is reported. For suitable substrates, the observed diastereoselectivities (up to 87:13) and enantioselectivities (>96% ee) are high.

Full text of DOI:10.1016/0957-4166(95)00059-X

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Product name:diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate

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