An improved preparation of diphenylmethylenecyclopropanes and their use in intramolecular palladium catalysed [3+2] cycloadditions

DOI: 10.1016/0040-4020(95)00051-9

Source and publish data:

Tetrahedron p. 3289 - 3302 (1995)

Update date:2022-07-29

Topics:

Authors:

Lewis, Richard T.

Motherwell, William B.

Shipman, Michael

Slawin, Alexandra M. Z.

Williams, David J.

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Article abstract of DOI:10.1016/0040-4020(95)00051-9

The synthesis and intramolecular palladium catalysed cycloaddition reactions of diphenylmethylenecyclopropanes 1 and 2 containing olefinic and acetylenic acceptors are described. This strategy provides a useful entry into some highly functionalised bicyclo[3.3.0]octane systems.

Full text of DOI:10.1016/0040-4020(95)00051-9

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