Palladium-Catalized Oxidative Cyclization of 1,5-Dienes. Influence of Diferent Substitution Patterns on the Regio- and Stereochemistry of the Reaction

DOI: 10.1021/jo00281a039

Source and publish data:

Journal of Organic Chemistry p. 4914 - 4929 (1989)

Update date:2022-08-05

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Authors:

Antonsson, Thomas

Moberg, Christina

Tottie, Louise

Heumann, Andreas

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Article abstract of DOI:10.1021/jo00281a039

Oxidative cyclization of 1,5-dienes in acetic acid in the presence of the Pd(II) regenerating catalyst system Pd(OAc)2/MnO2/p-benzoquinone has been shown to yield, depending on the structure of the 1,5-diene, acetoxyexomethylenecyclopentanes or acetoxyvin

Full text of DOI:10.1021/jo00281a039

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