Oxidation of amines in the presence of ruthenium complexes: Molecular oxygen and iodosylbenzene as oxidants

DOI: 10.1016/0304-5102(89)80289-5

Source and publish data:

Journal of molecular catalysis p. 333 - 341 (1989)

Update date:2022-09-26

Topics:

Authors:

Porta Porta

Crotti Crotti

Cenini Cenini

Palmisano

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Article abstract of DOI:10.1016/0304-5102(89)80289-5

The authors report here the characterization of the related complex with R = p-CH₃OC₆H₄. They report also the oxidation of secondary amines with molecular oxygen catalyzed by Ru(PPh₃)₃ Cl₂ and Ru(DMSO)₄Cl₂. A study has also been made of the oxidation of primary and secondary amines using iodosylbenzene, PhIO, as the oxidant. It is found that PhIO is a very active and selective oxidant in these reactions, its activity being negatively modified by the presence of Ru(PPh₃)₃Cl₂.

Full text of DOI:10.1016/0304-5102(89)80289-5

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Product name:Ru(PPh₃)(p-CH₃OC₆H₄CH₂NH₂)(p-CH₃OC₆H₄CN)Cl₂

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