Oxidation of amines in the presence of ruthenium complexes: Molecular oxygen and iodosylbenzene as oxidants

DOI: 10.1016/0304-5102(89)80289-5

Source and publish data:

Journal of molecular catalysis p. 333 - 341 (1989)

Update date:2022-09-26

Topics:

Authors:

Porta Porta

Crotti Crotti

Cenini Cenini

Palmisano

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0304-5102(89)80289-5

The authors report here the characterization of the related complex with R = p-CH₃OC₆H₄. They report also the oxidation of secondary amines with molecular oxygen catalyzed by Ru(PPh₃)₃ Cl₂ and Ru(DMSO)₄Cl₂. A study has also been made of the oxidation of primary and secondary amines using iodosylbenzene, PhIO, as the oxidant. It is found that PhIO is a very active and selective oxidant in these reactions, its activity being negatively modified by the presence of Ru(PPh₃)₃Cl₂.

Full text of DOI:10.1016/0304-5102(89)80289-5

Products guided by the article

Product name:Ru(PPh₃)(p-CH₃OC₆H₄CH₂NH₂)(p-CH₃OC₆H₄CN)Cl₂

Cas No:122836-11-7

R&D Labs maybe for 122836-11-7

shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
A-Chem Technologies Co.,Ltd.

Contact:+86-512-69561895

Address:No.111, Building A4, 218 Xinghu Street, Suzhou Industrial Park, P. R. China
Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Nanjing Spring & Autumn Biological Engineering Co., Ltd.

Contact:86-180510-83338

Address:Suite# 210, No. 1 BuildingNanjing Agricultural Biotechnology High-tech Entrepreneurship Center, No. 4 Tongwei Road, Xuanwu District, Nanjing,China
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China

Relevant to this article

Catalytic generation and trapping of acylmetals containing Ni and Cu with enolates

Doi:10.1016/S0040-4020(97)10210-1
(1998)
Ethyl 2-(tert-Butoxycarbonyloxyimino)-2-cyanoacetate (Boc-Oxyma): An Efficient Reagent for the Racemization Free Synthesis of Ureas, Carbamates and Thiocarbamates via Lossen Rearrangement

Doi:10.1002/adsc.201600661
(2017)
A new method for the preparation of nitrogen-containing cyclic compounds from p-nitrobenzenesulfonamide and alkyl bis(diphenylphosphinite)s by oxidation-reduction condensation using 1-azidoadamantane

Doi:10.1246/cl.2005.1644
(2005)
Activation of bis(guanidinate)lanthanide alkyl and aryl complexes on elemental sulfur: Synthesis and characterization of bis(guanidinate)lanthanide thiolates and disulfides

Doi:10.1021/ic100617n
(2010)
SEQUENTIAL ACETALIZATION-PYROLYSIS OF α-ACETYL BENZALACETONES. A METHOD FOR THE GENERATION OF 6-SUBSTITUTED 2-ACETONAPHTHONES

Doi:10.1016/S0040-4039(00)99489-9
(1989)
Synthesis and xanthine oxidase inhibitory activity of 7-methyl-2- (phenoxymethyl)-5H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one derivatives

Doi:10.1016/j.bmc.2010.11.034
(2011)

Article Doi