Journal of the Chemical Society. Perkin transactions I p. 279 - 281 (1989)
Update date:2022-08-05
Topics:
Matsuda, Yoshihiko
Tanimoto, Shigeo
Okamoto, Tadashi
Ali, Syed Mashhood
The reaction of α-keto esters with lithium 1,1,1,3,3,3-hexamethyldisilazanide afforded α-(N-trimethylsilyl)imino esters in good yields, which were reduced to the corresponding α-amino esters by reducing agents such as NaBH3CN. α-(N-Trimethylsilyl)imino esters were treated with methanol to afford 2-alkoxycarbonylimidazole-4(2H)-ones via dimerization of the intermediate α-imino esters.
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Doi:10.1016/S0020-1693(00)80897-X
(1989)Doi:10.1002/chem.200903586
(2010)Doi:10.1016/j.bmcl.2010.11.115
(2011)Doi:10.1021/es0106117
(2001)Doi:10.1016/S0040-4039(00)70658-7
(1989)Doi:10.1021/jo00298a018
(1990)
