Tetrahedron Letters p. 6713 - 6716 (1989)
Update date:2022-08-05
Topics: Purification and characterization Characterization and Verification Design the Retrosynthetic Analysis Scale-Up and Isolation Deprotection and final adjustments
Nunomura
Mori
Ito
Ogawa
A first total synthesis of Forssman antigen, GalNAcα1→3GalNAcβ1→3Galα1→4Galβ1→4Glcβ1-1Cer, was achieved in a stereoselective manner by using a glycopentaosyl fluoride as a key glycosyl donor for the crucial coupling with a ceramide equivalent.
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Doi:10.1039/c6nj00721j
(2016)Doi:10.1002/chir.23066
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(2011)
