
Tetrahedron Letters p. 1047 - 1050 (1989)
Update date:2022-08-02
Topics:
DeBruin, Kenneth E.
Boros, Eric E.
N-Substituted O,O-dimethyl N-benzoyl phosphoramidothioates (III, R=Me, Ph but not H) undergo an uncatalyzed unimolecular rearrangement in an inert solvent; whereby, the carbonyl oxygen atom exchanges position with the thiophosphoryl sulfur atom (an O,S Sw
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