European Journal of Organic Chemistry p. 2910 - 2920 (2010)
Update date:2022-09-26
Topics:
Gomez, Ana M.
Barrio, Aitor
Pedregosa, Ana
Uriel, Clara
Valverde, Serafin
Cristobal Lopez
Furanose- and pyranose-derived mono- and dihalo-exo-glycals undergo Sonogashira coupling reactions in the presence of Pd catalysts to give carbohydrate-derived enynes in a completely stereoselective manner. On the other hand, a furanose-derived 2, 3-anhydrohalo-exo-glycal, available from D-mannose in five steps, undergoes Pd0-catalyzed Sonogashira coupling, leading to 2-deoxyenynes.
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(2010)Doi:10.1016/j.bmcl.2009.05.094
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(2010)Doi:10.1039/c7nj05010k
(2018)
