Metal-assisted CO Labilization and Intramolecular Hydride Transfer Reactions in Heterobimetallic μ-Phosphido-Hydrido Carbonyl Complexes

DOI: 10.1039/c39840001149

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Journal of the Chemical Society. Chemical communications p. 1149 - 1150 (1984)

Update date:2022-08-03

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Authors:

Powell, John

Gregg, Michael R.

Sawyer, Jeffery F.

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Article abstract of DOI:10.1039/c39840001149

The oxidative addition of the P-H bond of (OC)5M(PPh2H) (M = Cr, Mo, W) to zerovalent platinum complexes initially forms heterobimetallic μ-phosphido terminal hydrido complexes which readily rearrange via bridging carbonyl and platinum-terminal carbonyl i

Full text of DOI:10.1039/c39840001149

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