Low-Valent Titanium-Induced Reductive Coupling of Amino Ketones

DOI: 10.1055/s-1989-27188

Source and publish data:

Synthesis p. 182 - 184 (1989)

Update date:2022-08-04

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Authors:

Chen, Wei-xing

Feng, Jun-cai

Zhou, Zhao-lin

Zhang, Jun-hu

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Article abstract of DOI:10.1055/s-1989-27188

The reaction of amino ketones with titanium tetrachloride/zinc powder has been studied in tetrahydrofuran and 1,4-dioxane under an argon atmosphere.Symmetrical 1,8-diaminoalkenes 2 were obtained from the corresponding Mannich base hydrochlorides 1 via the

Full text of DOI:10.1055/s-1989-27188

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