Tetrahedron Letters p. 2655 - 2658 (1988)
Update date:2022-07-30
Topics:
Coutrot, Ph.
Grison, C.
Dialkylphosphonoflouracetylchlorides are used to introduce directly the 2-oxophosphonate 1-fluorinated synthons on organometallic reagents.A Horner reaction of the 3 derivated anions with aldehydes gave various 2-fluoro-2-enones.Application to the cis, trans caronaldehyde ethyl ester led to the 2-fluoroethenyl pyrethroid derivatives.
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