SYNTHESE GENERALE DE β-CETOPHOSPHONATES α-FLUORES PRECURSEURS D'ENONES α-FLUOREES, APPLICATION EN SERIE PYRETHRENIQUE.

DOI: 10.1016/0040-4039(88)85251-1

Source and publish data:

Tetrahedron Letters p. 2655 - 2658 (1988)

Update date:2022-07-30

Topics:

Authors:

Coutrot, Ph.

Grison, C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(88)85251-1

Dialkylphosphonoflouracetylchlorides are used to introduce directly the 2-oxophosphonate 1-fluorinated synthons on organometallic reagents.A Horner reaction of the 3 derivated anions with aldehydes gave various 2-fluoro-2-enones.Application to the cis, trans caronaldehyde ethyl ester led to the 2-fluoroethenyl pyrethroid derivatives.

Full text of DOI:10.1016/0040-4039(88)85251-1

Products guided by the article

Product name:1-fluoro-2-oxobutylphosphonate de diethyle

Cas No:124050-40-4

R&D Labs maybe for 124050-40-4

NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
Jinan Jinguilin Chemical Co.,Ltd

Contact:+86-531-81188412

Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
ANHUI WEICHI CHEMICAL CO.,LTD

website:http://www.weichichem.com

Contact:+8613912949432

Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Shanghai PuYi Chem-Tech Co.,Ltd.

Contact:+86-21-57687505-227

Address:3 Floor, Building 11, No 201 MinYi Road, Songjiang District, Shanghai 201612, China

Relevant to this article

A NEW APPROACH TO THE SYNTHESIS OF A DIMERIC FRAGMENT OF THE CAPSULAR POLYSACCHARIDE OF HAEMOPHILUS INFLUENZAE type b

Doi:10.1016/S0040-4039(00)80414-1
(1988)
Diastereo- and enantioselective reductive aldol reaction with trichlorosilane using Chiral Lewis bases as organocatalysts

Doi:10.1002/asia.200900450
(2010)
Highly enantioselective hydrogenative desymmetrization of bicyclic imides leading to multiply functionalized chiral cyclic compounds

Doi:10.1021/ja105048c
(2010)
N-Acyldithieno[3,2- b:2′,3′-d]pyrroles: Second generation dithieno[3,2-b:2′,3′-d]pyrrole building blocks with stabilized energy levels

Doi:10.1021/ol101647f
(2010)
Nitrooxymethyl-substituted analogues of Rofecoxib: Synthesis and pharmacological characterization

Doi:10.1002/cbdv.200900421
(2010)
Synthesis and properties of the bipolar triphenylamine-benzimidazole derivatives

Doi:10.1071/CH09336
(2010)

Article Doi