Tetrahedron Letters p. 967 - 970 (1989)
Update date:2022-08-03
Topics:
Shimizu, Makoto
Yoshioka, Hirosuke
α,β-Epoxysilanes undergo the ring opening-fluorination with silicon tetrafluoride in the presence of diisopropylethylamine and water to give β-fluoro-β-silyl alcohols specifically, and the subsequent olefination with potassium hexamethyldisilazide affords fluoroalkenes in good yield.
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(1986)
