A TITANOXYCYCLOPROPANE AS INTERMEDIATE IN A HIGHLY STEREOSELECTIVE HOMOALDOL TYPE ADDITION SYNTHESES OF CIS-SUBSTITUTED TETRAHYDROFURAN DERIVATIVES

DOI: 10.1016/S0040-4020(01)80140-X

Source and publish data:

Tetrahedron p. 3139 - 3150 (1989)

Update date:2022-07-29

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Authors:

Reissig, Hans-Ulrich

Holzinger, Hiltrud

Glomsda, Gabriele

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Article abstract of DOI:10.1016/S0040-4020(01)80140-X

Reaction of methyl 2-siloxycyclopropanecarboxylate 4 with TiCl4 provides the unique titanoxycyclopropane 10 whose structure could be elucidated by means of NMR-spectroscopy.Its additions to aldehydes and acetophenone occur with high stereoselectivity to a

Full text of DOI:10.1016/S0040-4020(01)80140-X

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