Stereoselective Synthesis of (+/-)-Trichodiene

DOI: 10.1021/jo00301a036

Source and publish data:

Journal of Organic Chemistry p. 4403 - 4410 (1990)

Update date:2022-08-05

Topics:

Authors:

Harding, Kenn E.

Clement, K. S.

Tseng, C.-Y.

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Article abstract of DOI:10.1021/jo00301a036

Details of a convergent stereoselective synthesis of trichodiene (1) from simple monocyclic starting materials are reported.Stereochemical control is effected by Nazarov cyclization of dienone 14 and C-C bond cleavage of the resulting tricyclic products 1

Full text of DOI:10.1021/jo00301a036

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