EFFICIENT SYNTHESYS OF 2-VINYLCYCLOBUTANONES BY THE REARRANGEMENT OF 1-METHOXY-1-CYCLOPROPYLCARBINOLS UNDER NEUTRAL CONDITIONS

DOI: 10.1016/S0040-4020(01)80120-4

Source and publish data:

Tetrahedron p. 2917 - 2924 (1989)

Update date:2022-08-02

Topics:

Authors:

Cohen, Theodore

Brockunier, Linda

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Article abstract of DOI:10.1016/S0040-4020(01)80120-4

A common synthesis of cyclobutanones involves the rearrangement of 1-alkoxy- or 1-(phenylthio)cyclopropylcarbinols under acidic conditions.We report that the synthetically useful 2-vinylcyclobutanones can be prepared in good yield in the absence of proton

Full text of DOI:10.1016/S0040-4020(01)80120-4

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