Bicyclic bridgehead phosphoramidite (briphos) ligands with tunable π-acceptor ability and catalytic activity in the rhodium-catalyzed conjugate additions

DOI: 10.1021/ol502772m

Source and publish data:

Organic Letters p. 5490 - 5493 (2014)

Update date:2022-08-05

Topics:

Authors:

Lee, Ansoo

Ahn, Seihwan

Kang, Kyungjun

Seo, Min-Seob

Kim, Yeonjoon

Kim, Woo Youn

Kim, Hyunwoo

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Article abstract of DOI:10.1021/ol502772m

A new type of bicyclic bridgehead phosphoramidites (briphos) is reported, where the geometrical constraints significantly enhance the π-acceptor ability compared with its monocyclic analogs. The briphos is shown to be highly efficient and tunable for Rh(I

Full text of DOI:10.1021/ol502772m

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