SYNTHESIS OF EARTHY-MOULDY SMELLING COMPOUNDS-I STEREOSELECTIVE SYNTHESIS OF (+/-)-GEOSMIN

DOI: 10.1016/S0040-4039(00)99122-6

Source and publish data:

Tetrahedron Letters p. 2775 - 2778 (1989)

Update date:2022-09-26

Topics:

Authors:

Gosselin, P.

Joulain, D.

Laurin, P.

Rouessac, F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)99122-6

The strongly earthy-smelling compound (+/-)-geosmin 1 is obtained stereospecifically in four steps and 42percent overall yield from 1,4aβ-Dimethyl-4,4a,5,6,7,8-hexahydronaphtalen-2(3H)-one 2.The key step involves a one-pot double-reduction of an epoxytosylate.

Full text of DOI:10.1016/S0040-4039(00)99122-6

Products guided by the article

Product name:Toluene-4-sulfonic acid (1aS,4aR,8aR)-1a,4a-dimethyl-octahydro-1-oxa-cyclopropa[d]naphthalen-2-yl ester

Cas No:125107-10-0

R&D Labs maybe for 125107-10-0

Greenutra Resource Inc

website:http://www.greenutra.cn

Contact:0086-411-39553357

Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
SHOUGUANG BOYU CHEMICAL CO.,LTD

Contact:+86-536-8256719

Address:ROOM 1101&1103,BUILDING D,ZHONGTU MANSION,NO.6565 EAST FUSHOU STREET,WEIFANG CITY,SHANDONG,CHINA.
Shanghai Rich Chemicals Co., Ltd

website:http://www.richchemical.com

Contact:+86-21-20255798

Address:Pudong Shanghai,China
DU-HOPE INTERNATIONAL GROUP

Contact:+86-25-52346955

Address:199,JIANYE ROAD,NANJING,CHINA
NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,

Relevant to this article

A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using β-S-substituted aldehydes: The role of a hemilabile P-O-P ligand

Doi:10.1002/anie.200603133
(2006)
Novel method for synthesizing spiro[4.5]cyclohexadienones through a Pd-catalyzed intramolecular ipso-Friedel-Crafts allylic alkylation of phenols

Doi:10.1021/ol102190s
(2010)
A strategy to synthesize taxol side chain and (-)-epi cytoxazone via chiral Bronsted acid-Rh₂(OAc)₄ Co-catalyzed enantioselective three-component reactions

Doi:10.1021/jo101559p
(2010)
Total Synthesis of (±)-Integrifolin

Doi:10.1002/chem.201601275
(2016)
REACTIONS OF METHYL ESTERS OF SUBSTITUTED 2-AMINO-3,3,3-TRIFLUOROPROPIONIC ACIDS WITH ARYLAMINES

Doi:10.1007/BF00978448
(1989)
Synthesis of 1,2,3-Triazole-Fused Indole Derivatives via Copper-Catalyzed Cascade Reaction

Doi:10.1055/a-1364-9308
(2021)

Article Doi