A Regio-, (E)-Stereo-, and Chemo-selective Synthesis of Unsymmetrical Divinylmethanols starting from L- and D-Tartrates via Organocyanocopper Lewis Acid Mediated 1,3-chirality Transfer

DOI: 10.1039/c39890000967

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 967 - 969 (1989)

Update date:2022-08-04

Topics:

Authors:

Ibuka, Toshiro

Tanaka, Miwa

Yamamoto, Yoshinori

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890000967

A regio-, (E)-stereo-, and chemo-selective synthesis of synthetically useful unsymmetrical divinylmethanol derivatives, compounds that are not easily accessible by other means, via an organocyanocopper*Bf3 mediated 1,3-chirality transfer in mixed solvents

Full text of DOI:10.1039/c39890000967

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[(E)-(1R,4S)-5-Benzyloxy-1-((E)-3-benzyloxy-propenyl)-4-methyl-pent-2-enyloxy]-tert-butyl-dimethyl-silane

Cas No:125152-14-9

R&D Labs maybe for 125152-14-9

Suzhou Chiral Pharmaceuticals Co., Ltd.

Contact:86-0512-63197058

Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park
Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China
Beijing Wisdom Chemicals Co., Ltd.

Contact:+86-10-52350335

Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Shanghai FWD Chemicals ltd

website:http://www.fwdchem.com

Contact:86-21-54450828

Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
RongCheng K&S Chemical Co.,Ltd

Contact:0631-7336369

Address:rongcheng ,shandong province china

Relevant to this article

Synthesis and characterization of new N-alkylamino-3,5-diphenylpyrazole ligands and reactivity toward Pd^II and Pt^II. Study of the cis-trans isomerization

Doi:10.1071/CH09371
(2010)
Synthesis of mono-carbonyl analogues of curcumin and their effects on inhibition of cytokine release in LPS-stimulated RAW 264.7 macrophages

Doi:10.1016/j.bmc.2010.03.001
(2010)
Free-Radical Approach to C-C Bond Formation on a Trifluoromethyl-Substituted Carbon. Intramolecular Cyclization

Doi:10.1246/cl.1999.623
(1989)
Selective Synthesis of trans- and cis-p-Mentha-1,8-dien-5-ol from trans-Verbenol

Doi:10.1055/s-1988-27771
(1988)
Gold-catalyzed 1,2-oxoarylations of nitriles with pyridine-derived oxides

Doi:10.1002/anie.201403015
(2014)
Rh(I)-Catalyzed olefin hydroarylation with electron-deficient perfluoroarenes

Doi:10.1021/ja102575d
(2010)

Article Doi