A Convenient Horner-Emmons Approach to the Synthesis of Substituted Ethyl 1,3-Butadiene-2-carboxylates, and Related Compounds

DOI: 10.1055/s-1989-27301

Source and publish data:

Synthesis p. 506 - 510 (1989)

Update date:2022-08-03

Topics:

Authors:

Janecki, Tomasz

Bodalski, Ryszard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1989-27301

The Horner-Emmons reaction of the allylphosphonates 3 with aldehydes gives substituted 1,3-butadiene-2-carboxylates 12 in satisfactory yields.By suitable modification of reactants a variety of 3-alkenyl-2(5H)-furanones 13 and 3-alkenylcoumarins 14 are pre

Full text of DOI:10.1055/s-1989-27301

Products guided by the article

Product name:(E)-3-(Diethoxy-phosphoryl)-5-methyl-2-[1-phenyl-meth-(Z)-ylidene]-hex-3-enoic acid

Cas No:125155-11-5

R&D Labs maybe for 125155-11-5

Oceachem Group Limited

website:http://www.oceanchem-group.com

Contact:86-536-8596048

Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park
Yangzhou Zhongbao Pharmaceutical Co.,Ltd

Contact:+86-514-88290838

Address:Jiangsu Baoying county economic develpment zone in baoying avenue91
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone

Relevant to this article

Efficient enantioselective hetero-diels-alder reaction of brassard's diene with aliphatic aldehydes: A one-step synthesis of (R)-(+)-kavain and (S)-(+)-dihydrokavain

Doi:10.1021/ol8002282
(2008)
Preparation of optically active α-Silylcarbonyl compounds using asymmetric alkylation of α-Silylacetic esters and asymmetric metal-carbene insertion into the Si-H bond.

Doi:10.1016/S0040-4020(97)00002-1
(1997)
Mustard prodrugs for activation by Escherichia coli nitroreductase in gene-directed enzyme prodrug therapy

Doi:10.1021/jm960794l
(1997)
Synthesis, characterization and photophysical properties of [OsO₂(mes)₂(NC)Ru(bpy)₂(CN)]

Doi:10.1039/a607514b
(1997)
BIS(TETRAPHENYLCYCLOBUTADIEN)PALLADIUM(0)

Doi:10.1016/S0022-328X(00)84461-7
(1980)
Stereospecific, Stereoselective Rearrangement of Hexahydro-1,3-diazepin-2-ones to Tetrahydropyrimidin-2-ones and Imidazolidin-2-ones, a Useful Route for the Synthesis of HIV Protease Inhibitors

Doi:10.1021/jo980533e
(1998)

Article Doi