Organic and Biomolecular Chemistry p. 4074 - 4076 (2010)
Update date:2022-08-05
Topics:
Miura, Tomoya
Shimizu, Hiroshi
Igarashi, Tomohiro
Murakami, Masahiro
Vinyl-substituted (Z)-stilbenes are stereoselectively synthesised on treatment of 4-arylbuta-2,3-dien-1-ols with arylboronic acids in the presence of a rhodium(i) catalyst. The reaction proceeds through the regioselective addition of organorhodium(i) species across the aryl-substituted carbon-carbon double bond of the allene moiety and subsequent δ-elimination of Rh(i)-OH.
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