Synthesis and Some Reactions of 3,3,6-Trisubstituted Tricyclo1,4>heptan-2-ones

DOI: 10.1039/c39890000670

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 670 - 672 (1989)

Update date:2022-08-04

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Authors:

Finch, Harry

Highcock, Rona M.

Roberts, Stanley M.

Short, Kevin M.

Sik, Vladimir

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Article abstract of DOI:10.1039/c39890000670

Electrophiles and most nucleophiles react with tricyclo<3.2.0.0^1,4>heptan-2-ones with preferential cleavage of the C(1)-C(4) or C(1)-C(5) bond; X-ray data show the highly strained tricycloheptanone (14) has a bond angle of 149.2(9) deg at a tet

Full text of DOI:10.1039/c39890000670

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