Electron-rich iridium complexes. Metal-basicity-controlled chemoselectivity in hydrogen transfer reductions

DOI: 10.1016/0304-5102(90)85165-E

Source and publish data:

Journal of Molecular Catalysis p. 5 - 14 (1990)

Update date:2022-08-04

Topics:

Authors:

Farnetti, Erica

Kaspar, Jan

Graziani, Mauro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0304-5102(90)85165-E

α,β-unsaturated ketones are selectively reduced to allylic alcohols by hydrogen transfer from propan-2-ol catalyzed by [Ir(cod)X]₂ (X=Cl or CH₃O) in the presence of aminophosphines or using [H₂Ir(P-N(Me)CH₂(P-NM

Full text of DOI:10.1016/0304-5102(90)85165-E

Products guided by the article

Product name:{HIr(cyclo-octa-1,5-diene)(o-(diphenylphosphino)-N,N-dimethyl aniline)}

Cas No:125283-01-4

R&D Labs maybe for 125283-01-4

ANHUI WEICHI CHEMICAL CO.,LTD

website:http://www.weichichem.com

Contact:+8613912949432

Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Jiaxing Barton Chemicals

website:http://www.chinabarton.com

Contact:+86-573-82719618

Address:No. 162 Fumin Road, Honghe Town,
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
Jiangxi Huashi Pharmaceutical Co., Ltd

Contact:+86-795-4509628

Address:No.199, Ningbo Avenue, Fengxin industrial park, Fengxin county, Yichun city, Jiangxi
Lyan Limited

Contact:86-021-52418058

Address:8/F, Building 6, Guiping Road No.333, Shanghai, 200233, China

Relevant to this article

Alkyl-alkyl Suzuki cross-coupling of unactivated secondary alkyl chlorides

Doi:10.1002/anie.201003272
(2010)
Complexation of hydroxytyrosol with β-cyclodextrins. An efficient photoprotection

Doi:10.1016/j.tet.2010.08.009
(2010)
Synthesis of organogelling, fluoride ion-responsive, cholesteryl-based benzoxazole containing intra-and intermolecular hydrogen-bonding sites

Doi:10.1016/j.tetlet.2010.08.053
(2010)
Facile Cu-free Sonogashira cross-coupling of nucleoside C-6 arylsulfonates with terminal alkynes

Doi:10.1016/j.tet.2010.08.032
(2010)
Eleuthesides and their analogs: I. Synthesis of the base compound from levoglucosenone adduct with piperylene

Doi:10.1134/S1070428010080063
(2010)
Thermally induced intramolecular oxygen migration of N-oxides in atmospheric pressure chemical ionization mass spectrometry

Doi:10.1002/rcm.4706
(2010)

Article Doi