Electron-rich iridium complexes. Metal-basicity-controlled chemoselectivity in hydrogen transfer reductions

DOI: 10.1016/0304-5102(90)85165-E

Source and publish data:

Journal of Molecular Catalysis p. 5 - 14 (1990)

Update date:2022-08-04

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Authors:

Farnetti, Erica

Kaspar, Jan

Graziani, Mauro

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Article abstract of DOI:10.1016/0304-5102(90)85165-E

α,β-unsaturated ketones are selectively reduced to allylic alcohols by hydrogen transfer from propan-2-ol catalyzed by [Ir(cod)X]₂ (X=Cl or CH₃O) in the presence of aminophosphines or using [H₂Ir(P-N(Me)CH₂(P-NM

Full text of DOI:10.1016/0304-5102(90)85165-E

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