Triethylborane Induced Stereoselective Radical Addition of R3SiH to Acetylenes and Stereoselective Reduction of Alkenyl Iodides with Tris(trimethylsilyl)silane

DOI: 10.1246/bcsj.66.2356

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2356 - 2364 (1993)

Update date:2022-08-02

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Authors:

Miura, Katsukiyo

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1246/bcsj.66.2356

Triethylborane induced radical addition of various organosilanes (R3SiH) to acetylenes has been studied.Among them, tris(trimethylsilyl)silane (TTMSS) proved to be the best reagent for the hydrosilylation of acetylenic compounds in terms of yield and ster

Full text of DOI:10.1246/bcsj.66.2356

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