Convergent asymmetric disproportionation reactions: Metal/Bronsted acid relay catalysis for enantioselective reduction of quinoxalines

DOI: 10.1021/ja200723n

Source and publish data:

Journal of the American Chemical Society p. 6126 - 6129 (2011)

Update date:2022-07-29

Topics:

Authors:

Chen, Qing-An

Wang, Duo-Sheng

Zhou, Yong-Gui

Duan, Ying

Fan, Hong-Jun

Yang, Yan

Zhang, Zhang

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Article abstract of DOI:10.1021/ja200723n

A convergent asymmetric disproportionation of dihydroquinoxalines for the synthesis of chiral tetrahydroquinoxalines using a metal/Bronsted acid relay catalysis system has been developed. The use of hydrogen gas as the reductant makes the convergent dispr

Full text of DOI:10.1021/ja200723n

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