Tetrahedron p. 8076 - 8088 (2010)
Update date:2022-08-05
Topics: Asymmetric synthesis Phenols Experimental terms Chemical terms Hydroxyalkyl Stereodivergent
Davies, Stephen G.
Hume, W. Ewan
Roberts, Paul M.
Thomson, James E.
The use of the (S)-α-methylbenzyl group as a chiral auxiliary has allowed the diastereoselective ortho-deprotonation of a chromium tricarbonyl complexed phenoxy ring. When the resultant ortho-anion is treated with an aldehyde two diastereoisomeric complex
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