Controlling factors determining the regiochemistry of intramolecular alkoxymercuration

DOI: 10.1039/a608003k

Source and publish data:

Journal of the Chemical Society. Perkin Transactions 2 (2001) p. 1143 - 1146 (1997)

Update date:2022-08-05

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Authors:

Senda, Yasuhisa

Kanto, Hiroko

Itoh, Hiroki

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Article abstract of DOI:10.1039/a608003k

The intramolecular alkoxymercuration of (E)-5-arylpent-4-en-1-ols indicated that the regioselectivity is closely related to the Hammett constants of the para-substituents on the benzene ring. Large solvent effects on the regioselectivity were also observe

Full text of DOI:10.1039/a608003k

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