PREPARATIVE SYNTHESIS OF C-(α-D-GLUCOPYRANOSYL)-ALKENES AND -ALKADIENES : DIELS-ALDER REACTION

DOI: 10.1016/0008-6215(89)85066-9

Source and publish data:

Carbohydrate Research p. 223 - 230 (1989)

Update date:2022-09-26

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Authors:

Martin, Maria de Gracia Garcia

Horton, Derek

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Article abstract of DOI:10.1016/0008-6215(89)85066-9

The reaction of 2,3,4,6-tetra-O-benzyl-1-O-(p-nitrobenzoyl)-α-D-glucopyranose with (E)-penta-2,4-dienyltrimethylsilane and boron trifluoride etherate in acetonitrile afforded stereoselectivity (E)-5-(tetra-O-benzyl-α-D-glucopyranosyl)-1,3-pentadiene (1) i

Full text of DOI:10.1016/0008-6215(89)85066-9

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