Chemistry Letters p. 808 - 809 (2010)
Update date:2022-08-05
Topics:
Huddar, Sameerana N.
Mahajan, Ulhas S.
Akamanchi, Krishnacharya G.
A new reagent system, a combination of iodic acid and sodium nitrite has been investigated for oxidative coupling of N,N-disubstituted anilines. A facile para-selective coupling occurs to give benzidines at room temperature in water as a solvent. A tentative mechanism is proposed with some supporting experiments.
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(2010)Doi:10.1021/jo1018552
(2010)Doi:10.1016/j.ica.2010.03.030
(2010)Doi:10.1039/jr9610002498
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(2010)Doi:10.1039/c0cc02590a
(2010)
