Cleavage of an Aryl Carbon-Sulphur Bond in Hydride-Thiolate Complexes of Molybdenum(IV); X-Ray Crystal Structure of i3-2,4,6)(OMe)(PMePh2)>2(μ-S)2>

DOI: 10.1039/c39900001757

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1757 - 1759 (1990)

Update date:2022-08-02

Topics: Cleavage X-ray crystal structure

Authors:

Burrow, Timothy E.

Hills, Adrian

Hughes, David L.

Lane, Janette D.

Lazarowych, Natalie J.

et al. et al.

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Article abstract of DOI:10.1039/c39900001757

The complexes 1 (R = Me or Prⁱ; R' = Me or Et) in THF-MeOH decompose via cleavage of an aryl carbon-sulphur bond to give C6H3R3-2,4,6 and complexes <2(μ-S)2, 3 one of which (R = Pr View More

Full text of DOI:10.1039/c39900001757

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