Multiple bonds between main group elements and transition metals. LXIX. Condensation reactions of methyltrioxorhenium with 8-hydroxyquinoline and 2-hydroxyaniline: new rhenium(VII) chelate complexes

Article abstract of DOI:10.1016/0022-328X(81)80013-7

The title compound methyltrioxorhenium, (CH3ReO3, 1), reacts with 8-hydroxyquinoline at room temperature to give the dinuclear Re^VII complex 2O (2) in 90percent yield.A single crystal X-ray diffraction study has shown