Journal of Fluorine Chemistry p. 211 - 232 (1989)
Update date:2022-07-30
Topics:
Quinze
Laurent
Mison
Faure
Secondary aziridiness, substituted by a trifluoromethyl group were prepared by reacting Grignard reagents with oximes or a N,N,N-trimethylhydrazonium salt bearing a trifluoromethyl substituent. Contrary to the results obtained with hydrogenated substrates, ethyl magnesium bromide acted exclusively as a reducing agent. The structure of aziridine 5a was determined from X-ray crystallographic data.
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